VoiceOver keyboard shortcuts ‒ DefKey

0	VO + ⌘ Cmd + V	Find the next visited link
0	VO + ⌘ Cmd + ↑ Shift + V	Find the previous visited link
0	VO + ⌘ Cmd + E	Find the next misspelled word
0	VO + ⌘ Cmd + ↑ Shift + E	Find the previous misspelled word

0	VO + A	Read all text from the VoiceOver cursor to the end of the text
0	VO + ↑ Shift + A	Select all text in the VoiceOver cursor
0	VO + ⤶ Enter	Start and stop text selection in a text field (text selection tracking must be on)
0	VO + T	Speak text attributes
0	VO + ↑ Shift + 1	Add a hot spot in text
0	VO + 1	Jump to a hot spot in text
0	VO + P	Read paragraph in VoiceOver cursor
0	VO + Shift + Page Down	Read next paragraph
0	VO + Shift + Page Up	Read previous paragraph
0	VO + S	Read sentence in VoiceOver cursor
0	VO + Command + Page Down	Read next sentence
0	VO + Command + Page Up	Read previous sentence
0	VO + L	Read line in VoiceOver cursor
0	VO + ↓	Read next line
0	VO + ↑	Read previous line
0	VO + W	Read word in VoiceOver cursor
Press twice to hear the word spelled; press a third time to hear the word spelled phonetically.
0	VO + →	Read next word
0	VO + ←	Read previous word
0	VO + C	Read character in VoiceOver cursor
Press twice to hear the phonetic character.
0	VO + ↑ Shift + →	Read next character
0	VO + ↑ Shift + ←	Read previous character
0	VO + Home	Move to first visible word
0	VO + End	Move to last visible word
0	VO + ↑ Shift + Home	Move to beginning of text, scrolling if necessary
0	VO + ↑ Shift + End	Move to end of text, scrolling if necessary
0	VO + Space	Add new tab stop (in TextEdit only when the VoiceOver cursor is on a tab stop in the ruler)
0	VO + Del	Delete the current tab stop (in TextEdit only when the VoiceOver cursor is on a tab stop in the ruler)
0	VO + ↑ Shift + ↓	Interact with tab stop (in TextEdit only when the VoiceOver cursor is on a tab stop in the ruler)
0	VO + ↑ Shift + ↓ then ← →	Interact with tab stop: Move the stop
0	VO + F3	Reads the current word and character in the VoiceOver cursor
0	VO + F3 then F3	Reads the total number of lines and the number of visible lines in a document

0	VO + ⌘ Cmd + Y	Move to the next column
0	VO + ⌘ Cmd + ↑ Shift + Y	Move to the previous column
0	VO + ⌘ Cmd + F	Move to the next frame
0	VO + ⌘ Cmd + ↑ Shift + F	Move to the previous frame
0	VO + ⌘ Cmd + N	Move to the next auto web spot
0	VO + ⌘ Cmd + ↑ Shift + N	Move to the previous auto web spot
0	VO + ⌘ Cmd + ]	Move to the next web spot
0	VO + ⌘ Cmd + [	Move to the previous web spot
0	VO + U	Open the Web Item rotor
0	VO + A	Read from the current location on a webpage to the end of the page
0	VO + B	Read from the beginning of a webpage to the current location
0	VO + ↑ Shift + U	Read a link address (URL)
0	VO + Command + Page Down	Read the next sentence
0	VO + Command + Page Up	Read the previous sentence
0	VO + ↑ Shift + I	Read webpage statistics
0	VO + ⌘ Cmd + ↑ Shift + {	Remove a web spot
1	VO + ⌘ Cmd + ↑ Shift + }	Set a web spot
0	VO + ⌘ Cmd + ↑ Shift + } + }	Set the sweet spot
0	VO + =	Turn the grouping of items within a table on or off

VoiceOver supports gestures for multi-touch trackpads. We didn't cover them, you can visit Apple's VoiceOver page to learn those gestures.
Source: VoiceOver guide

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